全文获取类型
收费全文 | 18300篇 |
免费 | 1389篇 |
国内免费 | 790篇 |
专业分类
电工技术 | 455篇 |
综合类 | 1344篇 |
化学工业 | 7155篇 |
金属工艺 | 682篇 |
机械仪表 | 542篇 |
建筑科学 | 1614篇 |
矿业工程 | 458篇 |
能源动力 | 249篇 |
轻工业 | 435篇 |
水利工程 | 242篇 |
石油天然气 | 1802篇 |
武器工业 | 54篇 |
无线电 | 1337篇 |
一般工业技术 | 1825篇 |
冶金工业 | 316篇 |
原子能技术 | 91篇 |
自动化技术 | 1878篇 |
出版年
2024年 | 62篇 |
2023年 | 142篇 |
2022年 | 270篇 |
2021年 | 345篇 |
2020年 | 370篇 |
2019年 | 342篇 |
2018年 | 298篇 |
2017年 | 454篇 |
2016年 | 470篇 |
2015年 | 522篇 |
2014年 | 933篇 |
2013年 | 998篇 |
2012年 | 1339篇 |
2011年 | 1352篇 |
2010年 | 1085篇 |
2009年 | 1134篇 |
2008年 | 1051篇 |
2007年 | 1277篇 |
2006年 | 1177篇 |
2005年 | 1029篇 |
2004年 | 899篇 |
2003年 | 877篇 |
2002年 | 749篇 |
2001年 | 604篇 |
2000年 | 516篇 |
1999年 | 456篇 |
1998年 | 366篇 |
1997年 | 287篇 |
1996年 | 198篇 |
1995年 | 179篇 |
1994年 | 147篇 |
1993年 | 117篇 |
1992年 | 99篇 |
1991年 | 84篇 |
1990年 | 50篇 |
1989年 | 42篇 |
1988年 | 29篇 |
1987年 | 10篇 |
1986年 | 11篇 |
1985年 | 25篇 |
1984年 | 28篇 |
1983年 | 20篇 |
1982年 | 30篇 |
1981年 | 4篇 |
1980年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
针对未编码的多输入多输出(MIMO,Multi—Input Multi—Output)系统,提出一种复杂度适中的分组全分集全码率(GFDFR,Group—wise Full Diversity Full Rate)空时编码方案。该方案通过在发送端进行天线分组,各组独立编码,减小全分集全码率(FDFR,Full Diversity Full Rate)编码块的大小从而降低系统编解码复杂度;在频率选择性信道中,进一步对子载波分组进行独立编码,获得频率分集(或多径分集),以适中的复杂度在不降低系统分集度的情况下保证了信息的全码率传输,是一种在MIMO信道中极具实用价值的空时编码方案。 相似文献
42.
A series of new o‐phenylenediamine (OPD)/o‐phenetidine (PHT) copolymers with partly phenazine‐like structures has been successfully synthesized at three polymerization temperatures by chemically oxidative polymerization in four different polymerization media. The molecular structures and properties of the resulting OPD/PHT polymers were investigated by IR, UV–vis and high‐resolution 1H NMR spectroscopies, and DSC, in order to ascertain the effect of reaction temperature, comonomer ratio and acid medium. The copolymerization mechanism of OPD with PHT monomers has been proposed. It is found that the statistical OPD/PHT copolymer obtained at a temperature of 118 °C has a higher degree of polymerization than that obtained at 12–17 °C. The OPD content in the copolymers calculated from NMR spectroscopic analysis is higher than that in the feed OPD content, whereas the OPD content calculated from element analysis is slightly lower than the feed OPD content. It can be predicted that denitrogenation takes place in the OPD units during the polymerization process at OPD/PHT molar ratios of 90/10 and 100/0. These OPD/PHT copolymers exhibit a much better solubility than the OPD homopolymer, hence suggesting an incorporation of PHT units into the phenazine structure of the homopolymer. The thermal behavior of the copolymers was also studied. Copyright © 2004 Society of Chemical Industry 相似文献
43.
Fault-based side channel cryptanalysis is very effective against symmetric and asymmetric encryption algorithms. Although straightforward hardware and time redundancy based concurrent error detection (CED) architectures can be used to thwart such attacks, they entail significant overhead (either area or performance). In this paper we investigate two systematic approaches to low-cost, low-latency CED for symmetric encryption algorithm RC6. The proposed techniques have been validated on FPGA implementations of RC6, one of the advanced encryption standard finalists. 相似文献
44.
H.‐G. Boyen G. Kstle K. Zürn T. Herzog F. Weigl P. Ziemann O. Mayer C. Jerome M. Mller J.P. Spatz M.G. Garnier P. Oelhafen 《Advanced functional materials》2003,13(5):359-364
Starting with Co‐salt‐loaded inverse micelles, which form if the diblock copolymer polystyrene‐block‐poly(2‐vinylpyridine) is dissolved in a selective solvent like toluene and CoCl2 is added to the solution, monomicellar arrays of such micelles exhibiting a significant hexagonal order can be prepared on top of various substrates with tailored intermicellar distances and structure heights. In order to remove the polymer matrix and to finally obtain arrays of pure Co nanoparticles, the micelles are first exposed to an oxygen plasma, followed by a treatment in a hydrogen plasma. Applying in‐situ X‐ray photoelectron spectroscopy, it is demonstrated that: 1) The oxygen plasma completely removes the polymer, though conserving the original order of the micellar array. Furthermore, the resulting nanoparticles are entirely oxidized with a chemical shift of the Co 2p3/2 line pointing to the formation of Co3O4. 2) By the subsequent hydrogen plasma treatment the nanoparticles are fully reduced to metallic Co. 3) By exposing the pure Co nanoparticles for 100 s to various oxygen partial pressures pequation/tex2gif-inf-5.gif, a stepwise oxidation is observed with a still metallic Co core surrounded by an oxide shell. The data allow the extraction of the thickness of the oxide shell as a function of the total exposure to oxygen (pequation/tex2gif-inf-7.gif × time), thus giving the opportunity to control the ferromagnetic–antiferromagnetic composition of an exchange‐biased magnetic system. 相似文献
45.
茨21-133井CO2吞吐技术初步试验 总被引:1,自引:0,他引:1
茨榆坨油田茨13块原油属于普通稠油,1993年开始蒸汽吞吐采油,从第二轮开始效果明显变差,注汽返排率低,有效周期短,产量下降快,套管变形井增多。针对这些问题,在该区块茨21—133井进行CO2吞吐采油工艺现场试验,获得成功,增油效果明显。 相似文献
46.
A method for the synthesis of novel sulfated ionomer of styrene–butadiene–styrene triblock copolymer (SBS) was developed. SBS was first epoxidized by performic acid in the presence of a phase‐transfer catalyst; this was followed by a ring‐opening reaction with an aqueous solution of alkali salt of bisulfate. The optimum conditions for the ring‐opening reaction of the epoxidized SBS with an aqueous solution of KHSO4 were studied. During the ring‐opening reaction, both phase‐transfer catalyst and ring‐opening catalyst were necessary to enhance the conversion of epoxy groups to ionic groups. The products were characterized with Fourier transform infrared spectrophotometry and transmission electron microscopy (TEM). After the potassium ions of the ionomer were substituted with lead ions, the lead sulfated ionomer exhibited dark spots under TEM. Some properties of the sulfated ionomer were studied. With increasing ionic groups or ionic potential of the cations, the water absorbency and emulsifying volume of the ionomer and the intrinsic viscosity of the ionomer solution increased, whereas the oil absorbency decreased. The sulfated ionomer possessed excellent emulsifying properties compared with the sulfonated SBS ionomer. The sodium sulfated ionomers in the presence of 10% zinc stearate showed better mechanical properties than the original SBS. When the ionomer was blended with crystalline polypropylene, a synergistic effect occurred with respect to the tensile strength. The ionomer behaved as a compatibilizer for blending equal amounts of SBS and oil‐resistant chlorohydrin rubber. In the presence of 3% ionomer, the blend exhibited much better mechanical properties and solvent resistance than the blend without the ionomer. SEM photographs indicated improved compatibility between the two components of the blend in the presence of the ionomer. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
47.
Graft copolymers of sodium alginate (NaAlg) with N‐vinyl‐2‐pyrrolidone were prepared using azobisisobutyronitrile as initiator. The graft copolymers (NaAlg‐g‐PVP) were characterized with Fourier transform infrared spectroscopy, elemental analysis, and differential scanning calorimetry. Polymeric hydrogel beads of NaAlg and NaAlg‐g‐PVP were prepared by crosslinking method using glutaraldehyde (GA) as a crosslinker in the hydrochloric acid catalyst (HCl) and these beads were used to deliver anti‐inflammatory drug, indomethacin (IM). Chemical stability of the IM after encapsulation into beads was confirmed by FTIR. Preparation conditions of the NaAlg‐g‐PVP beads were optimized by considering the percentage entrapment efficiency, particle size, swelling capacity and their release data. In vitro release studies were performed in simulated gastric fluid (pH 1.2) for the initial 2 h, followed by simulated intestinal fluid (pH 7.4) for 4 h. Effects of GA concentration, exposure time to GA, drug/polymer (d/p) ratio, and concentration of HCl on the release of IM were discussed. It was observed that IM release from the beads decreased with increasing GA concentration and exposure time. IM release also decreases with increasing d/p ratio and HCl concentration. The highest IM release was obtained to be 77% for beads crosslinked with 0.027M GA. Swelling experiments were also performed to compute molecular mass between crosslinks of the beads. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
48.
Crystal phase transition between the low- and high-temperature phases has been investigated for ethylene (E)-tetrafluoroethylene (TFE) alternating copolymer (ETFE) containing the third monomeric species by the temperature dependent measurements of wide-angle X-ray diffraction (WAXD) and small-angle X-ray scattering (SAXS) and differential scanning calorimetry. Nonafluoro-1-hexene (NFH) and hexafluoropropylene (HFP) were chosen as the third monomers, where they are different in the side-branch length, -(CF2)3CF3 and -CF3, respectively. In the case of E/TFE/NFH copolymer (ET-C4F9), the crystal phase transition temperature of the original ETFE two-components copolymer was not very much affected by the existence of NFH in the range of NFH content from 0.7 to 3 mol%. Contrarily, the crystal phase transition temperature of E/TFE/HFP copolymer (ET-CF3) was found to decrease drastically with increasing HFP content. The melting temperature and the higher-order structure were also affected sensitively depending on the HFP content. This difference in phase transition behavior between ET-C4F9 and ET-CF3 copolymers is reasonably interpreted as follows: the short side groups (-CF3) of HFP monomeric unit are included in the crystal lattice of E/TFE chains and the unit cell is expanded gradually with an increment of the HFP content, resulting in the decrease in phase transition point because of easier thermal motion of the chains. On the other hand, the long side groups [-(CF2)3CF3] of NFH monomeric units are excluded out of the crystal lattice and located on the lamellar surfaces or in the amorphous region and do not affect very much the phase transition temperature even when the NFH content is increased. In association with such a change in crystal structure, the long period of stacked lamellar structure was found to decrease remarkably in the case of NFH, whereas it does not change very much for HFP, consistent with the interpretation of the above-mentioned WAXD data. 相似文献
49.
通过对锯切装置的改进,提高了锯切性能,降低了锯条成本,保证了锯切质量,使设备更加高效、安全的工作。 相似文献
50.